2.5.1.71: leachianone-G 2''-dimethylallyltransferase

This is an abbreviated version!
For detailed information about leachianone-G 2''-dimethylallyltransferase, go to the full flat file.

Reaction

Synonyms

leachianone G 2''-dimethylallyltransferase, LG 2''-dimethylallyltransferase, LGDT

ECTree

     2 Transferases

         2.5 Transferring alkyl or aryl groups, other than methyl groups

             2.5.1 Transferring alkyl or aryl groups, other than methyl groups (only sub-subclass identified to date)

                2.5.1.71 leachianone-G 2''-dimethylallyltransferase

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Results	in table
2	KM Value [mM]
3	Localization
8	Metals/Ions
1	Natural Substrates/ Products (Substrates)
1	Organism
1	Pathway
1	pH Optimum
1	pH Range
1	Purification (Commentary)
2	Reaction
1	Reference
1	Source Tissue
2	Specific Activity [micromol/min/mg]
4	Substrates and Products (Substrate)
3	Synonyms
1	Systematic Name
1	Temperature Optimum [°C]

Substrates Products

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Substrates Products on EC 2.5.1.71 - leachianone-G 2''-dimethylallyltransferase

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SUBSTRATE

PRODUCT                       

REACTION DIAGRAM

ORGANISM

UNIPROT

COMMENTARY
(Substrate)

LITERATURE
(Substrate)

COMMENTARY
(Product)

LITERATURE
(Product)

Reversibility
r=reversible
ir=irreversible
?=not specified

dimethylallyl diphosphate + euchrenone a7

diphosphate + ?

Sophora flavescens

-

54% of the activity with leachianone G

676566

-

-

?

dimethylallyl diphosphate + leachianone G

diphosphate + sophoraflavanone G

2 entries

additional information

?

-

Sophora flavescens

-

no activity with isopentenyl diphosphate and geranyl diphosphate as prenyl donors, and with kenusanone I, 8-dimethylallylnaringenin, and isovabachin as acceptor substrates, overview

676566

-

-

?

dimethylallyl diphosphate + leachianone G

diphosphate + sophoraflavanone G

Sophora flavescens

-

the enzyme transfers a dimethylallyl group to the 2'' position of another dimethylallyl group attached at position 8 of leachianone G to form sophoraflavanone G, a branched monoterpenoid-conjugated flavanone characteristic to this plant

676566

-

-

?

dimethylallyl diphosphate + leachianone G

diphosphate + sophoraflavanone G

Sophora flavescens

-

the enzyme is a prenyl side-chain elongation enzyme, the enzyme transfers a dimethylallyl group to the 2'' position of another dimethylallyl group attached at position 8 of leachianone G to form sophoraflavanone G, a branched monoterpenoid-conjugated flavanone, the enzyme is absolutely specific for dimethylallyl diphosphate as prenyl donor and highly specific for leachianone G, the 2'-hydroxy function in leachianone G is indispensable to the activity

676566

-

-

?