2.5.1.124: 6-linalyl-2-O,3-dimethylflaviolin synthase

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For detailed information about 6-linalyl-2-O,3-dimethylflaviolin synthase, go to the full flat file.

Reaction

Synonyms

Fur7

ECTree

2 Transferases

2.5 Transferring alkyl or aryl groups, other than methyl groups

2.5.1 Transferring alkyl or aryl groups, other than methyl groups (only sub-subclass identified to date)

2.5.1.124 6-linalyl-2-O,3-dimethylflaviolin synthase

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Results	in table
4	AA Sequence
1	Cloned(Commentary)
4	General Information
4	kcat/KM [mM/s]
8	KM Value [mM]
2	Metals/Ions
2	Natural Substrates/ Products (Substrates)
3	Organism
1	pH Optimum
1	Purification (Commentary)
1	Reaction
2	Reference
11	Substrates and Products (Substrate)
2	Synonyms
1	Systematic Name
1	Temperature Optimum [°C]
4	Turnover Number [1/s]

Substrates Products

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Substrates Products on EC 2.5.1.124 - 6-linalyl-2-O,3-dimethylflaviolin synthase

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dimethylallyl diphosphate + flaviolin

2 entries

geranyl diphosphate + 1,3-dihydroxynaphthalene

2 entries

geranyl diphosphate + 2-O-methyl-3-methylflaviolin

diphosphate + (E)-7-((3,7-dimethylocta-2,6-dien-1-yl)oxy)-5-hydroxy-2-methoxy-3-methylnaphthalene-1,4-dione + 6-prenyl-2-methoxy-3-methylflaviolin

2 entries

geranyl diphosphate + 2-O-methyl-3-methylflaviolin

diphosphate + 6-(3,7-dimethylocta-1,6-dien-3-yl)-5,7-dihydroxy-2-methoxy-3-methylnaphthalene-1,4-dione

2 entries

geranyl diphosphate + flaviolin

diphosphate + 2-[(2E)-3,7-dimethylocta-2,6-dien-1-yl]-3,6,7-trihydroxynaphthalene-1,4-dione

Streptomyces sp.

i.e. 2,5,7-trihydroxynaphthalene-1,4-dione. The kcat/Km of the prenylation of flaviolin is significantly higher than that of the prenylation of the natural substrate 2-O-methyl-3-methylflaviolin

725410

geranyl diphosphate + flaviolin

diphosphate + 3-[(2E)-3,7-dimethylocta-2,6-dien-1-yl]-2,5,7-trihydroxynaphthalene-1,4-dione

2 entries