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2.5.1.120: aminodeoxyfutalosine synthase

This is an abbreviated version!
For detailed information about aminodeoxyfutalosine synthase, go to the full flat file.

Reaction

S-adenosyl-L-methionine
+
3-[(1-carboxyvinyl)oxy]benzoate
+
H2O
=
6-amino-6-deoxyfutalosine
+
L-methionine
+
HCO3-

Synonyms

AFL synthase, aminofutalosine synthase, MqnE, TTHA0804

ECTree

     2 Transferases
         2.5 Transferring alkyl or aryl groups, other than methyl groups
             2.5.1 Transferring alkyl or aryl groups, other than methyl groups (only sub-subclass identified to date)
                2.5.1.120 aminodeoxyfutalosine synthase

Natural Substrates Products

Natural Substrates Products on EC 2.5.1.120 - aminodeoxyfutalosine synthase

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NATURAL SUBSTRATE
NATURAL PRODUCT
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
REVERSIBILITY
r=reversible
ir=irreversible
?=not specified
S-adenosyl-L-methionine + 3-[(1-carboxyvinyl)oxy]benzoate + H2O
6-amino-6-deoxyfutalosine + L-methionine + bicarbonate
show the reaction diagram
the enzyme is part of the futalosine pathway for menaquinone biosynthesis
6-amino-6-deoxyfutalosine i.e. 3-[3-[(2R,3S,4R,5R)-5-(6-amino-9H-purin-9-yl)-3,4-dihydroxytetrahydrofuran-2-yl]propanoyl]benzoate
-
?
S-adenosyl-L-methionine + 3-[(1-carboxyvinyl)oxy]benzoate + H2O
6-amino-6-deoxyfutalosine + L-methionine + HCO3-
show the reaction diagram