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2.4.1.B65: 4-hydroxy-3-methoxybenzyl alcohol alpha-D-glucosyltransferase

This is an abbreviated version!
For detailed information about 4-hydroxy-3-methoxybenzyl alcohol alpha-D-glucosyltransferase, go to the full flat file.

Reaction

Vanillyl alcohol
+
maltose
=
4-hydroxy-3-methoxybenzyl alpha-D-glucopyranoside
+
D-glucose

Synonyms

maltase

ECTree

     2 Transferases
         2.4 Glycosyltransferases
             2.4.1 Hexosyltransferases
                2.4.1.B65 4-hydroxy-3-methoxybenzyl alcohol alpha-D-glucosyltransferase

Substrates Products

Substrates Products on EC 2.4.1.B65 - 4-hydroxy-3-methoxybenzyl alcohol alpha-D-glucosyltransferase

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SUBSTRATE
PRODUCT                       
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
vanillyl alcohol + maltose
4-hydroxy-3-methoxybenzyl alpha-D-glucopyranoside + D-glucose
show the reaction diagram
-
-
-
?
vanillyl alcohol + maltose
vanillyl alcohol alpha-D-glucoside + D-glucose
show the reaction diagram
-
-
-
?
vanillyl alcohol alpha-D-glucoside + maltose
vanillyl alcohol alpha-D-isomaltoside + D-glucose
show the reaction diagram
-
at low vanillyl alcohol concentrations up to 50 mM, or if the reaction is prolonged to 3 h at higher concentrations of vanillyl alcohol, additional transglucosylation product vanillyl alcohol alpha-isomaltoside is detected. The transglucosidation takes place at the C6 hydroxyl group of vanillyl alcohol alpha-D-glucoside
-
?
additional information
?
-
enzyme additionally catalyses the reaction of alpha-glucosidase/maltase, EC 3.2.1.20. The Km value of the enzyme for maltose in the synthetic reaction to vanillyl alcohol alpha-glucoside is about two times smaller than in maltose hydrolysis
-
-
?