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2.3.1.95: trihydroxystilbene synthase

This is an abbreviated version!
For detailed information about trihydroxystilbene synthase, go to the full flat file.

Word Map on EC 2.3.1.95

Reaction

3 malonyl-CoA +

4-coumaroyl-CoA
= 4 CoA +
trans-resveratrol
 + 4 CO2

Synonyms

AhSTS3, malonyl-CoA:4-coumaroyl-CoA malonyltransferase, resveratrol synthase, SbCHS8, SbSTS1, stilbene synthase, stilbene synthase 1, stilbene synthase 3, stilbene synthase-type polyketide synthase enzyme, STS, STS-type PKS enzyme, STS1, STS29, STS6, STS7, synthase, resveratrol, VIT_16s0100g01030, VIT_16s0100g01040, vst1

ECTree

     2 Transferases
         2.3 Acyltransferases
             2.3.1 Transferring groups other than aminoacyl groups
                2.3.1.95 trihydroxystilbene synthase

Substrates Products

Substrates Products on EC 2.3.1.95 - trihydroxystilbene synthase

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SUBSTRATE
PRODUCT                       
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
3 malonyl-CoA + 4-coumaroyl-CoA
4 CoA + resveratrol + 4 CO2
show the reaction diagram
-
out of three enzymes tested, only stilbene synthase from Arachis hypogaea is able to produce resveratrol from 4-coumaric acid
-
?
3 malonyl-CoA + 4-coumaroyl-CoA
4 CoA + trans-resveratrol + 4 CO2
show the reaction diagram
3-coumaroyl-CoA + malonyl-CoA
3,3',5-trihydroxystilbene + CoA + CO2
show the reaction diagram
-
9% of activity with 4-coumaroyl-CoA
-
?
4-coumaroyl-CoA + malonyl-CoA
3,4',5-trihydroxystilbene + CoA + CO2
show the reaction diagram
4-fluorocinnamoyl-CoA + malonyl-CoA
4'-fluoro-trans-3,5-dihydroxystyrylfuran + CoA + CO2
show the reaction diagram
-
side products: 49% bis-noryangonin and its derivatives, 8.2% 4-coumaroyltriacetic acid and 0.7% chalcone and its derivatives
?
acetyl-CoA + malonyl-CoA
6-acetonyl-4-hydroxy-2-pyrone + 6-methyl-4-hydroxy-2-pyrone + CoA + CO2
show the reaction diagram
-
-
?
benzoyl-CoA + malonyl-CoA
bisnoryangonin-type and p-coumaroyltriacetic acid lactone-type pyrones + CoA + CO2
show the reaction diagram
-
-
?
caffeoyl-CoA + malonyl-CoA
3,3',4',5-tetrahydroxystilbene + CoA + CO2
show the reaction diagram
-
8% of activity with 4-coumaroyl-CoA
-
?
cinnamoyl-CoA + malonyl-CoA
3,5-dihydroxystilbene + CoA + CO2
show the reaction diagram
dihydro-4-coumaroyl-CoA + malonyl-CoA
3,4',5-trihydroxybibenzyl + CoA + CO2
show the reaction diagram
-
13% of activity with 4-coumaroyl-CoA
-
?
feruloyl-CoA + malonyl-CoA
3,4',5-trihydroxy-3'-methoxystilbene + CoA + CO2
show the reaction diagram
-
6% of activity with 4-coumaroyl-CoA
-
?
isovaleryl-CoA + malonyl-CoA
bisnoryangonin-type and p-coumaroyltriacetic acid lactone-type pyrones + CoA + CO2
show the reaction diagram
-
-
?
n-butyryl-CoA + malonyl-CoA
bisnoryangonin-type and p-coumaroyltriacetic acid lactone-type pyrones + CoA + CO2
show the reaction diagram
-
-
?
n-hexanoyl-CoA + malonyl-CoA
bisnoryangonin-type and p-coumaroyltriacetic acid lactone-type pyrones + CoA + CO2
show the reaction diagram
-
-
?
trans-3-(3-thienyl)acryloyl-CoA + malonyl-CoA
trans-3,5-dihydroxystyrylthiophene + CoA + CO2
show the reaction diagram
-
side products: 59% bis-noryangonin and its derivatives, 18.4% 4-coumaroyltriacetic acid and 0.5% chalcone and its derivatives
?
trans-3-furanacryloyl-CoA + malonyl-CoA
trans-3,5-dihydroxystyrylfuran + CoA + CO2
show the reaction diagram
-
side products: 32% bis-noryangonin and its derivatives, 15% 4-coumaroyltriacetic acid and 0.6% chalcone and its derivatives
?
additional information
?
-