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2.3.1.160: vinorine synthase

This is an abbreviated version!
For detailed information about vinorine synthase, go to the full flat file.

Word Map on EC 2.3.1.160

Reaction

acetyl-CoA
+
16-epivellosimine
=
CoA
+
vinorine

Synonyms

More, vinorine synthase, VS

ECTree

     2 Transferases
         2.3 Acyltransferases
             2.3.1 Transferring groups other than aminoacyl groups
                2.3.1.160 vinorine synthase

Systematic Name

Systematic Name on EC 2.3.1.160 - vinorine synthase

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SYSTEMATIC NAME
IUBMB Comments
acyl-CoA:16-epivellosimine O-acetyltransferase (cyclizing)
The reaction proceeds in two stages. The indole nitrogen of 16-epivellosimine interacts with its aldehyde group giving an hydroxy-substituted new ring. This alcohol is then acetylated. Also acts on gardneral (11-methoxy-16-epivellosimine). Generates the ajmalan skeleton, which forms part of the route to ajmaline.