2.3.1.160: vinorine synthase
This is an abbreviated version!
For detailed information about vinorine synthase, go to the full flat file.
Word Map on EC 2.3.1.160
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2.3.1.160
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rauvolfia
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ajmaline
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acyltransferases
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serpentina
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antiarrhythmic
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indole
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monoterpenoid
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morphine
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gardneral
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hanging-drop
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coa-dependent
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hxxxd
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vindoline
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strictosidine
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deacetylvindoline
- 2.3.1.160
- rauvolfia
- ajmaline
- acyltransferases
- serpentina
-
antiarrhythmic
- indole
-
monoterpenoid
- morphine
- gardneral
-
hanging-drop
-
coa-dependent
-
hxxxd
- vindoline
- strictosidine
- deacetylvindoline
Reaction
Synonyms
More, vinorine synthase, VS
ECTree
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Systematic Name
Systematic Name on EC 2.3.1.160 - vinorine synthase
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acyl-CoA:16-epivellosimine O-acetyltransferase (cyclizing)
The reaction proceeds in two stages. The indole nitrogen of 16-epivellosimine interacts with its aldehyde group giving an hydroxy-substituted new ring. This alcohol is then acetylated. Also acts on gardneral (11-methoxy-16-epivellosimine). Generates the ajmalan skeleton, which forms part of the route to ajmaline.