2.3.1.144: anthranilate N-benzoyltransferase
This is an abbreviated version!
For detailed information about anthranilate N-benzoyltransferase, go to the full flat file.
Word Map on EC 2.3.1.144
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2.3.1.144
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gold
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alloy
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dianthus
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dental
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caryophyllus
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carnation
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healthcare
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phytoalexins
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hardening
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4-coumaroyl-coa
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hardness
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cinnamates
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synthesis
- 2.3.1.144
- gold
-
alloy
- dianthus
-
dental
- caryophyllus
- carnation
-
healthcare
-
phytoalexins
-
hardening
- 4-coumaroyl-coa
-
hardness
- cinnamates
- synthesis
Reaction
Synonyms
anthranilate N-hydroxycinammoyl/benzoyltransferase, benzoyl-CoA/anthranilate N-hydroxycinnamoyl/benzoyltransferase, benzoyltransferase, anthranilate N-, HCBT, hydroxycinnamoyl/benzoyl-CoA/anthranilate N-hydroxycinnamoyl/benzoyltransferase, hydroxycinnamoyl/benzoyl-CoA/anthranilate N-hydroxycinnamoyl/benzoyltransferase
ECTree
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Substrates Products
Substrates Products on EC 2.3.1.144 - anthranilate N-benzoyltransferase
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REACTION DIAGRAM
2,3-dimethoxycinnamoyl-CoA + 3-hydroxyanthranilate
CoA + N-(2,3-dimethoxycinnamoyl)-3-hydroxyanthranilate
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-
-
?
2,3-dimethoxycinnamoyl-CoA + anthranilate
CoA + N-(2,3-dimethoxycinnamoyl)-anthranilate
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-
-
?
2,4-dimethoxycinnamoyl-CoA + anthranilate
CoA + N-(2,4-dimethoxycinnamoyl)-anthranilate
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-
-
?
2,5-dimethoxycinnamoyl-CoA + 3-hydroxyanthranilate
CoA + N-(2,5-dimethoxycinnamoyl)-3-hydroxyanthranilate
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-
-
?
2,5-dimethoxycinnamoyl-CoA + anthranilate
CoA + N-(2,5-dimethoxycinnamoyl)-anthranilate
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-
-
?
2-coumaroyl-CoA + 3-hydroxyanthranilate
CoA + N-(2-coumaroyl)-3-hydroxyanthranilate
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-
-
?
2-coumaroyl-CoA + anthranilate
CoA + N-(2-coumaroyl)anthranilate
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-
-
?
3,4,5-trimethoxycinnamoyl-CoA + 3-hydroxyanthranilate
CoA + N-(3,4,5-trimethoxycinnamoyl)-3-hydroxyanthranilate
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-
-
?
3,4,5-trimethoxycinnamoyl-CoA + anthranilate
CoA + N-(3,4,5-trimethoxycinnamoyl)-anthranilate
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-
-
?
3,4-dimethoxycinnamoyl-CoA + 3-hydroxyanthranilate
CoA + N-(3,4-dimethoxycinnamoyl)-3-hydroxyanthranilate
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-
-
?
3-coumaroyl-CoA + 3-hydroxyanthranilate
CoA + N-(3-coumaroyl)-3-hydroxyanthranilate
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-
-
?
3-coumaroyl-CoA + anthranilate
CoA + N-(3-hydroxycinnamoyl)-anthranilate
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-
-
?
3-hydroxy-4-methoxycinnamoyl-CoA + anthranilate
CoA + N-(3-hydroxy-4-methoxycinnamoyl)-anthranilate
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-
-
?
3-methoxycinnamoyl-CoA + 3-hydroxyanthranilate
CoA + N-(3-methoxycinnamoyl)-3-hydroxyanthranilate
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-
-
?
3-methoxycinnamoyl-CoA + anthranilate
CoA + N-(3-methoxycinnamoyl)-anthranilate
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-
-
?
4-coumaroyl-CoA + 3-hydroxyanthranilate
CoA + N-(4-coumaroyl)-3-hydroxyanthranilate
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-
-
?
4-coumaroyl-CoA + anthranilate
CoA + N-(4-coumaroyl)-anthranilate
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product detection by mass spectrometry
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?
4-methoxycinnamoyl-CoA + anthranilate
CoA + N-(4-methoxycinnamoyl)-anthranilate
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-
-
?
benzoyl-CoA + 3-hydroxyanthranilate
CoA + N-benzoyl-3-hydroxyanthranilate
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20% of activity with anthranilate
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?
benzoyl-CoA + 4-hydroxyanthranilate
CoA + N-benzoyl-4-hydroxyanthranilate
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10% of activity with anthranilate
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?
caffeoyl-CoA + 3-hydroxyanthranilate
CoA + N-caffeoyl-3-hydroxyanthranilate
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-
-
?
caffeoyl-CoA + anthranilate
CoA + N-(3,4-dihydroxycinnamoyl)-anthranilate
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-
-
?
cinnamoyl-CoA + 3-hydroxyanthranilate
CoA + N-cinnamoyl-3-hydroxyanthranilate
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-
-
?
coumaroyl-CoA + anthranilate
CoA + N-(4-hydroxycinnamoyl)-anthranilate
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product detection by mass spectrometry
-
?
feruloyl-CoA + 3-hydroxyanthranilate
CoA + N-feruloyl-3-hydroxyanthranilate
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-
-
?
feruloyl-CoA + anthranilate
CoA + N-feruloylanthranilate
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-
-
?
salicyl-CoA + anthranilate
CoA + N-salicylanthranilate
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60% of activity with benzoyl-CoA
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-
?
sinapoyl-CoA + 3-hydroxyanthranilate
CoA + N-sinapoyl-3-hydroxyanthranilate
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-
-
?
sinapoyl-CoA + anthranilate
CoA + N-sinapoylanthranilate
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-
-
?
CoA + N-4-(coumaroyl)anthranilate
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-
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?
4-coumaroyl-CoA + anthranilate
CoA + N-4-(coumaroyl)anthranilate
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127% of activity with benzoyl-CoA
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-
?
benzoyl-CoA + anthranilate
CoA + N-benzoylanthranilate
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cinnamoyl-CoA, salicyl-CoA and 4-coumaroyl-CoA can act as donors
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?
benzoyl-CoA + anthranilate
CoA + N-benzoylanthranilate
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cinnamoyl-CoA, salicyl-CoA and 4-coumaroyl-CoA can act as donors
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?
benzoyl-CoA + anthranilate
CoA + N-benzoylanthranilate
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cinnamoyl-CoA, salicyl-CoA and 4-coumaroyl-CoA can act as donors with 73%, 70% and 65% efficiency respectively, enzyme is involved in the biosynthesis of phytoalexins, 4-hydroxyanthranilate is the most probable substrate in vivo
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?
CoA + N-cinnamoylanthranilate
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-
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?
cinnamoyl-CoA + anthranilate
CoA + N-cinnamoylanthranilate
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140% of activity with benzoyl-CoA
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-
?
?
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hydroxycinnamoyl/benzoyl-CoA/anthranilate N-hydroxycinnamoyl/benzoyltransferase, HCBT, has affinity for anthranilate and 4-coumaroyl-CoA and is capable of producing N-(4-hydroxycinnamoyl)-anthranilate in vitro
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?
additional information
?
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hydroxycinnamoyl/benzoyl-CoA/anthranilate N-hydroxycinnamoyl/benzoyltransferase, HCBT, has affinity for anthranilate and 4-coumaroyl-CoA and is capable of producing N-(4-hydroxycinnamoyl)-anthranilate in vitro
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?
additional information
?
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by exploiting the substrate flexibility of both 4-coumaroyl:CoA ligase 4CL5 from Arabidopsis thaliana and HCBT, rapid biosynthesis of more than 160 cinnamoyl, dihydrocinnamoyl, and benzoyl anthranilates in yeast can be achieved. The enzyme offers flexibility for a wide range of acyl-CoA donors, its affinity towards acceptors seems limited to anthranilates
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?