2.3.1.111: mycocerosate synthase
This is an abbreviated version!
For detailed information about mycocerosate synthase, go to the full flat file.
Word Map on EC 2.3.1.111
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2.3.1.111
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mycobacterium
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bovis
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tuberculosis
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synthases
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smegmatis
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polyketide
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acyl-coa
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phthiocerol
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dimycocerosate
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n-fatty
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esterify
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kolattukudy
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methyl-branched
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beta-ketoacyl
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resequenced
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hygromycin-resistant
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synthase-like
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crossover
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iterative
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phenolphthiocerol
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fadd28
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rainwater
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slow-growing
- 2.3.1.111
- mycobacterium
- bovis
- tuberculosis
- synthases
- smegmatis
- polyketide
- acyl-coa
- phthiocerol
-
dimycocerosate
-
n-fatty
-
esterify
-
kolattukudy
-
methyl-branched
-
beta-ketoacyl
-
resequenced
-
hygromycin-resistant
-
synthase-like
-
crossover
-
iterative
- phenolphthiocerol
-
fadd28
-
rainwater
-
slow-growing
Reaction
+ 3 methylmalonyl-CoA + 6 NADPH + 6 H+ = + 3 CoA + 3 CO2 + 6 NADP+ + 3 H2O
Synonyms
mycocerosic acid synthase, Pks5
ECTree
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Substrates Products
Substrates Products on EC 2.3.1.111 - mycocerosate synthase
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REACTION DIAGRAM
eicosanoyl-CoA + 4 methylmalonyl-CoA + 4 NADPH
2,4,6,8-tetramethyloctacosanoyl-CoA + 4 CoA + 4 CO2 + 4 NADP+
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?
eicosanoyl-CoA + 4 methylmalonyl-CoA + 8 NADPH + 8 H+
tetramethyl-branched mycocerosoyl-CoA + 4 CoA + 4 CO2 + 8 NADP+ + 4 H2O
tetramethyl-branched mycocerosoyl-CoA + 4 CoA + 4 CO2 + 8 NADP+ + 4 H2O
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?
eicosanoyl-CoA + 4 methylmalonyl-CoA + 8 NADPH + 8 H+
tetramethyl-branched mycocerosoyl-CoA + 4 CoA + 4 CO2 + 8 NADP+ + 4 H2O
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multifunctional enzyme, specific for methylmalonyl-CoA, cannot be replaced by malonyl-CoA, n-acyl-CoAs of C-6 to C-20 are substrates
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