2.1.1.326: N-acetyldemethylphosphinothricin P-methyltransferase
This is an abbreviated version!
For detailed information about N-acetyldemethylphosphinothricin P-methyltransferase, go to the full flat file.
Reaction
2 S-adenosyl-L-methionine + + = + + + +
Synonyms
BcpD, P-methylase, PhpK, SD_1168
ECTree
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Natural Substrates Products
Natural Substrates Products on EC 2.1.1.326 - N-acetyldemethylphosphinothricin P-methyltransferase
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REACTION DIAGRAM
2 S-adenosyl-L-methionine + N-acetyldemethylphosphinothricin + reduced acceptor
S-adenosyl-L-homocysteine + 5'-deoxyadenosine + L-methionine + N-acetylphosphinothricin + oxidized acceptor
N-acetyldemethylphosphinothricin i.e. (2S)-2-acetamido-4-phosphinatobutanoate. In vivo the enzyme acts on N-acetyldemethylphosphinothricin-L-alanyl-L-alanine or N-acetyl-demethylphosphinothricin-L-alanyl-L-leucine, the intermediates in the biosynthesis of the tripeptides bialaphos and phosalacine (which inhibit plant and bacterial glutamine synthetases)
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