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2.1.1.239: L-olivosyl-oleandolide 3-O-methyltransferase

This is an abbreviated version!
For detailed information about L-olivosyl-oleandolide 3-O-methyltransferase, go to the full flat file.

Reaction

S-adenosyl-L-methionine
+
L-olivosyl-oleandolide
=
S-adenosyl-L-homocysteine
 +
L-oleandrosyl-oleandolide

Synonyms

OleY

ECTree

     2 Transferases
         2.1 Transferring one-carbon groups
             2.1.1 Methyltransferases
                2.1.1.239 L-olivosyl-oleandolide 3-O-methyltransferase

Substrates Products

Substrates Products on EC 2.1.1.239 - L-olivosyl-oleandolide 3-O-methyltransferase

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SUBSTRATE
PRODUCT                       
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
S-adenosyl-L-methionine + L-mycarosyl-erythronolide B
S-adenosyl-L-homocysteine + ?
show the reaction diagram
poor substrate
-
-
?
S-adenosyl-L-methionine + L-olivosyl-erythronolide B
S-adenosyl-L-homocysteine + L-oleandrosyl-erythronolide B
show the reaction diagram
S-adenosyl-L-methionine + L-rhamnosyl-erythronolide B
S-adenosyl-L-homocysteine + ?
show the reaction diagram
-
-
-
?
additional information
?
-
no bioconversion is observed when other glycosylated macrolide antibiotics (spiramycin, niddamycin, carbomycin) are added to cultures of Streptomyces albus NAG2(pLR14b-4). These three macrolides contain L-mycarose moieties with a free 3-hydroxy group but are not methylated by OleY
-
-
?