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1.14.99.12: androst-4-ene-3,17-dione monooxygenase

This is an abbreviated version!
For detailed information about androst-4-ene-3,17-dione monooxygenase, go to the full flat file.

Word Map on EC 1.14.99.12

Reaction

androstenedione
+
reduced acceptor
+
O2
=
testololactone
+
acceptor
+
H2O

Synonyms

4-androstene-3,17-dione monooxygenase, androst-4-ene-3,17-dione 17-oxidoreductase, androst-4-ene-3,17-dione hydroxylase, androstene-3,17-dione hydroxylase, androstenedione monooxygenase, oxygenase, androstenedione mono-

ECTree

     1 Oxidoreductases
         1.14 Acting on paired donors, with incorporation or reduction of molecular oxygen
             1.14.99 Miscellaneous
                1.14.99.12 androst-4-ene-3,17-dione monooxygenase

Reaction

Reaction on EC 1.14.99.12 - androst-4-ene-3,17-dione monooxygenase

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REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
androstenedione + reduced acceptor + O2 = testololactone + acceptor + H2O
show the reaction diagram
FNR is able to transfer electrons between one-electron carriers, ferredoxin or flavodoxin, and two-electron carriers, NADP+ and NADPH, involving its redox cofactor FAD, involvement of Glu312 in the FNR catalytic mechanism not only as a proton donor but also as a key residue for stabilizing and destabilizing reaction intermediates, reaction mechanism and catalytic cycle, overview
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