1.14.19.15: (11Z)-hexadec-11-enoyl-CoA conjugase

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For detailed information about (11Z)-hexadec-11-enoyl-CoA conjugase, go to the full flat file.

Reaction

+ 2 H2O

Synonyms

Bmpgdesat1, desat1, PG Z11/DELTA10,12 desaturase, pgdesat1

ECTree

1 Oxidoreductases

1.14 Acting on paired donors, with incorporation or reduction of molecular oxygen

1.14.19 With oxidation of a pair of donors resulting in the reduction of O₂ to two molecules of water

1.14.19.15 (11Z)-hexadec-11-enoyl-CoA conjugase

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Systematic Name on EC 1.14.19.15 - (11Z)-hexadec-11-enoyl-CoA conjugase

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(11Z)-hexadec-11-enoyl-CoA,reduced acceptor:oxygen 10,13-allylic oxidase (10E,12E-forming)

The enzyme, characterized from the silk moth Bombyx mori, catalyses a step in the pathway for the biosynthesis of bombykol, a sex pheromone produced by the moth. The enzyme converts a single cis double bond at position 11 of (11Z)-hexadec-11-enoyl-CoA into conjugated 10 trans and 12 cis double bonds. Prior to catalysing this reaction, the enzyme catalyses the introduction of the cis bond in position 11 (cf. EC 1.14.19.5, acyl-CoA 11-desaturase).