1.14.13.92: phenylacetone monooxygenase
This is an abbreviated version!
For detailed information about phenylacetone monooxygenase, go to the full flat file.
Word Map on EC 1.14.13.92
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1.14.13.92
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baeyer-villiger
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ketone
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enantioselectivity
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bvmos
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thermobifida
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biocatalytic
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cyclohexanone
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fusca
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synthesis
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sulfoxidations
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biocatalyst
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phosphite
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cyclopentanone
- 1.14.13.92
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baeyer-villiger
- ketone
-
enantioselectivity
-
bvmos
-
thermobifida
-
biocatalytic
- cyclohexanone
- fusca
- synthesis
-
sulfoxidations
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biocatalyst
- phosphite
- cyclopentanone
Reaction
Synonyms
4-hydroxyacetophenone monooxygenase, Baeyer-Villiger monooxygenase, BVMO, EtaA, HAPMO, M-PAMO, More, PAMO, phenylacetone monooxygenase, Tf PAMO
ECTree
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Turnover Number
Turnover Number on EC 1.14.13.92 - phenylacetone monooxygenase
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additional information
additional information
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all substrates show a turnover between 1.2 s-1 and 3.6 s-1
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2.3
2-Octanone
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mutant enzyme P253F/G254A/R258M/L443F, at pH 7.5 and 37°C
2.3
2-Octanone
recombinant mutant P253F/G254A/R258M/L443F, pH 7.4, 25°C
0.07
recombinant wild-type enzyme, pH 7.4, 25°C
0.3
2-phenylcyclohexanone
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mutant enzyme P253F/G254A/R258M/L443F, at pH 7.5 and 37°C
0.3
2-phenylcyclohexanone
recombinant mutant P253F/G254A/R258M/L443F, pH 7.4, 25°C
0.156
cyclohexanone
pH 8.0, 25°C, recombinant mutant S441G/A442P/L443T/S444Q
1.6
Cyclopentanone
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mutant enzyme P253F/G254A/R258M/L443F, at pH 7.5 and 37°C
1.6
Cyclopentanone
recombinant mutant P253F/G254A/R258M/L443F, pH 7.4, 25°C
0.04
phenylacetone
recombinant mutant P253F/G254A/R258M/L443F, pH 7.4, 25°C
0.26
phenylacetone
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25°C, pH 8.5, in the presence of 0.006 mM bovine serum albumin
1.4
phenylacetone
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mutant enzyme P253F/G254A/R258M/L443F, at pH 7.5 and 37°C