1.14.13.92: phenylacetone monooxygenase
This is an abbreviated version!
For detailed information about phenylacetone monooxygenase, go to the full flat file.
Word Map on EC 1.14.13.92
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1.14.13.92
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baeyer-villiger
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ketone
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enantioselectivity
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bvmos
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thermobifida
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biocatalytic
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cyclohexanone
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fusca
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synthesis
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sulfoxidations
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biocatalyst
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phosphite
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cyclopentanone
- 1.14.13.92
-
baeyer-villiger
- ketone
-
enantioselectivity
-
bvmos
-
thermobifida
-
biocatalytic
- cyclohexanone
- fusca
- synthesis
-
sulfoxidations
-
biocatalyst
- phosphite
- cyclopentanone
Reaction
Synonyms
4-hydroxyacetophenone monooxygenase, Baeyer-Villiger monooxygenase, BVMO, EtaA, HAPMO, M-PAMO, More, PAMO, phenylacetone monooxygenase, Tf PAMO
ECTree
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Reference on EC 1.14.13.92 - phenylacetone monooxygenase
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REF. 
AUTHORS
TITLE
JOURNAL
VOL.
PAGES
YEAR
ORGANISM (UNIPROT)
PUBMED ID
SOURCE
Fraaije, M.W.; Wu, J.; Heuts, D.P.; van Hellemond, E.W.; Spelberg, J.H.; Janssen, D.B.
Discovery of a thermostable Baeyer-Villiger monooxygenase by genome mining
Appl. Microbiol. Biotechnol.
66
393-400
2005
Thermobifida fusca
Fraaije, M.W.; Kamerbeek, N.M.; Heidekamp, A.J.; Fortin, R.; Janssen, D.B.
The prodrug activator EtaA from Mycobacterium tuberculosis is a Baeyer-Villiger monooxygenase
J. Biol. Chem.
279
3354-3360
2004
Mycobacterium tuberculosis
Malito, E.; Alfieri, A.; Fraaije, M.W.; Mattevi, A.
Crystal structure of a Baeyer-Villiger monooxygenase
Proc. Natl. Acad. Sci. USA
101
13157-13162
2004
Thermobifida fusca (Q47PU3), Thermobifida fusca
Bocola, M.; Schulz, F.; Leca, F.; Vogel, A.; Fraaije, M.W.; Reetz, M.T.
Converting phenylacetone monooxygenase into phenylcyclohexanone monooxygenase by rational design: towards practical Baeyer-Villiger monooxygenases
Adv. Synth. Catal.
347
979-986
2005
Thermobifida fusca
-
Schulz, F.; Leca, F.; Hollmann, F.; Reetz, M.T.
Towards practical biocatalytic Baeyer-Villiger reactions: applying a thermostable enzyme in the gram-scale synthesis of optically active lactones in a two-liquid-phase system
Beilstein J. Org. Chem.
1
10
2005
Thermobifida fusca
De Gonzalo, G.; Ottolina, G.; Zambianchi, F.; Fraaije, M.W.; Carrea, G.
Biocatalytic properties of Baeyer-Villiger monooxygenases in aqueous-organic media
J. Mol. Catal. B
39
91-97
2006
Thermobifida fusca
-
de Gonzalo, G.; Torres Pazmino, D.E.; Ottolina, G.; Fraaije, M.W.; Carrea, G.
Oxidations catalyzed by phenylacetone monooxygenase from Thermobifida fusca
Tetrahedron
16
3077-3083
2005
Thermobifida fusca
-
Rehdorf, J.; Kirschner, A.; Bornscheuer, U.T.
Cloning, expression and characterization of a Baeyer-Villiger monooxygenase from Pseudomonas putida KT2440
Biotechnol. Lett.
29
1393-1398
2007
Pseudomonas putida, Pseudomonas putida KT 2240
Zambianchi, F.; Fraaije, M.W.; Carrea, G.; de Gonzalo, G.; Rodriguez, C.; Gotor, V.; Ottolina, G.
Titration and assignment of residues that regulate the enantioselectivity of phenylacetone monooxygenase
Adv. Synth. Catal.
349
1327-1331
2007
Thermobifida fusca (Q47PU3)
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Torres Pazmino, D.E.; Baas, B.J.; Janssen, D.B.; Fraaije, M.W.
Kinetic mechanism of phenylacetone monooxygenase from Thermobifida fusca
Biochemistry
47
4082-4093
2008
Thermobifida fusca (Q47PU3), Thermobifida fusca
Rodriguez, C.; de Gonzalo, G.; Torres Pazmino, D.E.; Fraaije, M.W.; Gotor, V.
Selective Baeyer-Villiger oxidation of racemic ketones in aqueous-organic media catalyzed by phenylacetone monooxygenase
Tetrahedron Asymmetry
19
197-203
2008
Thermobifida fusca
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Rioz-Martinez, A.; De Gonzal, D.G.; Torres Pazmino, D.; Fraaije, M.; Gotor, V.
Enzymatic Baeyer-Villiger oxidation of benzo-fused ketones: Formation of regiocomplementary lactones
Eur. J. Org. Chem.
2009
2526-2532
2009
Pseudomonas fluorescens, Thermobifida fusca
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Reetz, M.T.; Wu, S.
Laboratory evolution of robust and enantioselective Baeyer-Villiger monooxygenases for asymmetric catalysis
J. Am. Chem. Soc.
131
15424-15432
2009
Thermobifida fusca
Dudek, H.M.; Torres Pazmino, D.E.; Rodriguez, C.; de Gonzalo, G.; Gotor, V.; Fraaije, M.W.
Investigating the coenzyme specificity of phenylacetone monooxygenase from Thermobifida fusca
Appl. Microbiol. Biotechnol.
88
1135-1143
2010
Thermobifida fusca
Dudek, H.M.; de Gonzalo, G.; Pazmino, D.E.; Stepniak, P.; Wyrwicz, L.S.; Rychlewski, L.; Fraaije, M.W.
Mapping the substrate binding site of phenylacetone monooxygenase from Thermobifida fusca by mutational analysis
Appl. Environ. Microbiol.
77
5730-5738
2011
Thermobifida fusca
Dudek, H.M.; Fink, M.J.; Shivange, A.V.; Dennig, A.; Mihovilovic, M.D.; Schwaneberg, U.; Fraaije, M.W.
Extending the substrate scope of a Baeyer-Villiger monooxygenase by multiple-site mutagenesis
Appl. Microbiol. Biotechnol.
98
4009-4020
2013
Thermobifida fusca
de Gonzalo, G.; Rodriguez, C.; Rioz-Martinez, A.; Gotor, V.
Improvement of the biocatalytic properties of one phenylacetone monooxygenase mutant in hydrophilic organic solvents
Enzyme Microb. Technol.
50
43-49
2012
Thermobifida fusca
Andrade, L.; Pedrozo, E.; Leite, H.; Brondani, P.
Oxidation of organoselenium compounds. A study of chemoselectivity of phenylacetone monooxygenase
J. Mol. Catal. B
73
63-66
2011
Thermobifida fusca
-
Rodriguez, C.; De Gonzalo, G.; Gotor, V.
Optimization of oxidative bioconversions catalyzed by phenylacetone monooxygenase from Thermobifida fusca
J. Mol. Catal. B
74
138-143
2012
Thermobifida fusca
-
Parra, L.P.; Acevedo, J.P.; Reetz, M.T.
Directed evolution of phenylacetone monooxygenase as an active catalyst for the Baeyer-Villiger conversion of cyclohexanone to caprolactone
Biotechnol. Bioeng.
112
1354-1364
2015
Thermobifida fusca (Q47PU3)
Carvalho, A.T.P.; Dourado, D.F.A.R.; Skvortsov, T.; de Abreu, M.; Ferguson, L.J.; Quinn, D.J.; Moody, T.S.; Huang, M.
Catalytic mechanism of phenylacetone monooxygenases for non-native linear substrates
Phys. Chem. Chem. Phys.
19
26851-26861
2017
Thermobifida fusca (Q47PU3)
Gran-Scheuch, A.; Parra, L.; Fraaije, M.
Systematic assessment of uncoupling in flavoprotein oxidases and monooxygenases
ACS Sust. Chem. Eng.
FEHLT
0000
2021
Thermobifida fusca (Q47PU3)
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Seo, E.; Kim, M.; Park, S.; Park, S.; Oh, D.; Bornscheuer, U.; Park, J.
Enzyme access tunnel engineering in Baeyer-Villiger monooxygenases to improve oxidative stability and biocatalyst performance
Adv. Synth. Catal.
364
555-564
2022
Thermobifida fusca (Q47PU3)
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Parshin, P.D.; Pometun, A.A.; Martysuk, U.A.; Kleymenov, S.Y.; Atroshenko, D.L.; Pometun, E.V.; Savin, S.S.; Tishkov, V.I.
Effect of His6-tag position on the expression and properties of phenylacetone monooxygenase from Thermobifida fusca
Biochemistry (Moscow)
85
575-582
2020
Thermobifida fusca (Q47PU3), Thermobifida fusca
Purwani, N.N.; Martin, C.; Savino, S.; Fraaije, M.W.
Modular assembly of phosphite dehydrogenase and phenylacetone monooxygenase for tuning cofactor regeneration
Biomolecules
11
905
2021
Thermobifida fusca (Q47PU3)
Yang, G.; Cang, R.; Shen, L.; Xue, F.; Huang, H.; Zhang, Z.
Expanding the substrate scope of phenylacetone monooxygenase from Thermobifida fusca towards cyclohexanone by protein engineering
Catal. Commun.
119
159-163
2019
Thermobifida fusca (Q47PU3)
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