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1.14.13.208: benzoyl-CoA 2,3-epoxidase

This is an abbreviated version!
For detailed information about benzoyl-CoA 2,3-epoxidase, go to the full flat file.

Word Map on EC 1.14.13.208

Reaction

benzoyl-CoA
+
NADPH
+
H+
+
O2
=
2,3-epoxy-2,3-dihydrobenzoyl-CoA
+
NADP+
+
H2O

Synonyms

benzoyl coenzyme A epoxidase, benzoyl-CoA 2,3-dioxygenase, benzoyl-CoA dioxygenase/reductase, benzoyl-CoA epoxidase, benzoyl-CoA oxygenase, benzoyl-coenzyme A epoxidase, BoxA, BoxA/BoxB system, BoxAB, BoxB, BoxBA, EC 1.14.12.21

ECTree

     1 Oxidoreductases
         1.14 Acting on paired donors, with incorporation or reduction of molecular oxygen
             1.14.13 With NADH or NADPH as one donor, and incorporation of one atom of oxygen into the other donor
                1.14.13.208 benzoyl-CoA 2,3-epoxidase

Systematic Name

Systematic Name on EC 1.14.13.208 - benzoyl-CoA 2,3-epoxidase

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SYSTEMATIC NAME
IUBMB Comments
benzoyl-CoA,NADPH:oxygen oxidoreductase (2,3-epoxydizing)
The enzyme is involved in aerobic benzoate metabolism in Azoarcus evansii. BoxB functions as the oxygenase part of benzoyl-CoA oxygenase in conjunction with BoxA, the reductase component, which upon binding of benzoyl-CoA, transfers two electrons to the ring in the course of monooxygenation. BoxA is a homodimeric 46 kDa iron-sulfur-flavoprotein (FAD), BoxB is a monomeric iron-protein [1].