1.14.13.187: L-evernosamine nitrososynthase

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For detailed information about L-evernosamine nitrososynthase, go to the full flat file.

Reaction

Synonyms

DnmZ, nitrososynthase, ORF36

ECTree

     1 Oxidoreductases

         1.14 Acting on paired donors, with incorporation or reduction of molecular oxygen

             1.14.13 With NADH or NADPH as one donor, and incorporation of one atom of oxygen into the other donor

                1.14.13.187 L-evernosamine nitrososynthase

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3	AA Sequence
7	Cofactor
2	Crystallization (Commentary)
3	General Information
3	Natural Substrates/ Products (Substrates)
8	Organism
8	PDB ID
10	Reaction
8	Reference
13	Substrates and Products (Substrate)
2	Subunits
6	Synonyms
1	Systematic Name

Systematic Name

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Systematic Name on EC 1.14.13.187 - L-evernosamine nitrososynthase

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SYSTEMATIC NAME

IUBMB Comments

dTDP-beta-L-evernosamine,NADPH:oxygen oxidoreductase (N-hydroxylating)

Requires FAD. Isolated from the bacterium Micromonospora carbonacea var. africana. The nitroso group is probably spontaneously oxidized to a nitro group giving dTDP-beta-L-evernitrose, which is involved in the biosynthesis of the antibiotic everninomycin. The reaction was studied using dTDP-beta-L-4-epi-vancosamine (dTDP-4-O-desmethyl-beta-L-evernitrosamine).