1.14.13.187: L-evernosamine nitrososynthase

This is an abbreviated version!
For detailed information about L-evernosamine nitrososynthase, go to the full flat file.

Word Map on EC 1.14.13.187

1.14.13.187

thymidine

monooxygenase

micromonospora

anthracycline

flavin-dependent

africana

peucetius

Reaction

+ 2 NADPH + 2 H+ + 2 O2 =

dTDP-2,3,6-trideoxy-3-C-methyl-4-O-methyl-3-nitroso-beta-L-arabino-hexopyranose

+ 2 NADP⁺ + 3 H2O

Synonyms

DnmZ, nitrososynthase, ORF36

ECTree

1 Oxidoreductases

1.14 Acting on paired donors, with incorporation or reduction of molecular oxygen

1.14.13 With NADH or NADPH as one donor, and incorporation of one atom of oxygen into the other donor

1.14.13.187 L-evernosamine nitrososynthase

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Results	in table
3	AA Sequence
7	Cofactor
2	Crystallization (Commentary)
3	General Information
3	Natural Substrates/ Products (Substrates)
8	Organism
8	PDB ID
10	Reaction
8	Reference
13	Substrates and Products (Substrate)
2	Subunits
6	Synonyms
1	Systematic Name

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Reference on EC 1.14.13.187 - L-evernosamine nitrososynthase

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725191

Hu, Y.; Al-Mestarihi, A.; Grimes, C.L.; Kahne, D.; Bachmann, B.O.

A unifying nitrososynthase involved in nitrosugar biosynthesis

J. Am. Chem. Soc.

130

15756-15757

2008

Micromonospora carbonacea, Micromonospora carbonacea var. africana

18983146

726951

Vey, J.; Al-Mestarihi, A.; Hu, Y.; Funk, M.; Bachmann, B.; Iverson, T.

Structure and mechanism of ORF36, an amino sugar oxidizing enzyme in everninomicin biosynthesis

Biochemistry

9306-9317

2010

Micromonospora carbonacea (B5APQ9), Micromonospora carbonacea ATCC 39149 (B5APQ9)

20866105

727686

Al-Mestarihi, A.; Romo, A.; Liu, H.; Bachmann, B.

Nitrososynthase-triggered oxidative carbon-carbon bond cleavage in baumycin biosynthesis

J. Am. Chem. Soc.

135

11457-11460

2013

Streptomyces peucetius (O33706), Streptomyces peucetius

23885759

728170

Li, Y.; Ding, L.; Zhang, Q.; Wang, W.

MD and QM/MM study on catalytic mechanism of a FAD-dependent enzyme ORF36: For nitro sugar biosynthesis

J. Mol. Graph. Model.

9-16

2013

Micromonospora sp. (B5APQ9), Micromonospora sp. ATCC 39149 (B5APQ9)

23735899

743958

Sartor, L.; Ibarra, C.; Al-Mestarihi, A.; Bachmann, B.O.; Vey, J.L.

Structure of DnmZ, a nitrososynthase in the Streptomyces peucetius anthracycline biosynthetic pathway

Acta Crystallogr. Sect. F

1205-1214

2015

Streptomyces peucetius (A0A0R4I990), Streptomyces peucetius

26457508