1.13.11.73: methylphosphonate synthase
This is an abbreviated version!
For detailed information about methylphosphonate synthase, go to the full flat file.
Word Map on EC 1.13.11.73
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1.13.11.73
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dioxygenase
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oxygenases
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nonheme
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h-abstraction
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methane
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ocean
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deprotonate
- 1.13.11.73
- dioxygenase
- oxygenases
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nonheme
-
h-abstraction
- methane
-
ocean
-
deprotonate
Reaction
Synonyms
methylphosphonate synthase, mpnS
ECTree
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Substrates Products
Substrates Products on EC 1.13.11.73 - methylphosphonate synthase
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REACTION DIAGRAM
(R)-2-hydroxyethylphosphonate + O2
methylphosphonate + HCO3-
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?
(S)-2-hydroxyethylphosphonate + O2
methylphosphonate + HCO3-
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-
-
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?
2-hydroxyethylphosphonate + O2
methylphosphonate + HCO3-
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-
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?
2-hydroxyethylphosphonate + O2
methylphosphonate + HCO3-
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enzyme catalyzes the asymmetric oxidation of hydroxyethylphosphonate, with all four electrons being derived from the C-2 carbon
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?
2-hydroxyethylphosphonate + O2
methylphosphonate + HCO3-
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stereospecific hydrogen transfer of the pro-R hydrogen at C2 of the substrate to the methyl group of methylphosphonate. Neither hydrogen transfer is rate limiting under saturating substrate conditions
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?
2-hydroxyethylphosphonate + O2
methylphosphonate + HCO3-
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the pro-(R) hydrogen at C2 of 2-hydroxyethylphosphonate is quantitatively incorporated by enzyme MPnS into methylphosphonate. AN irreversible step involving O2
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ir
2-hydroxyethylphosphonate + O2
methylphosphonate + HCO3-
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?