1.13.11.59: torulene dioxygenase
This is an abbreviated version!
For detailed information about torulene dioxygenase, go to the full flat file.
Word Map on EC 1.13.11.59
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1.13.11.59
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neurosporaxanthin
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carotene
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apocarotenoids
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neurospora
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carotenoid
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crassa
- 1.13.11.59
- neurosporaxanthin
- carotene
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apocarotenoids
- neurospora
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carotenoid
- crassa
Reaction
Synonyms
Cao-2, Cao2, carotenoid oxygenase, CarT
ECTree
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Substrates Products
Substrates Products on EC 1.13.11.59 - torulene dioxygenase
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REACTION DIAGRAM
3,4-didehydrolycopene + O2
apo-4'-lycopenal + 3-methylbut-2-enal
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Cao2 accepts both cyclic and acyclic carotenals
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-
?
beta-apo-10'-carotenal + O2
retinal + 3-methylbut-2-enal
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i.e. beta-apo-15'-carotenal
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?
beta-apo-8'-carotenal + O2
beta-apo-14'-carotenal + 3-methylbut-2-enal
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-
-
?
beta-apo-8'-lycopenal + O2
crocetindial + ?
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main product. Substrate contains both a non-oxygenated tail and an aldehyde end group, reaction leads mainly to the dialdehyde
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?
beta-apo-4'-carotenal + 3-methylbut-2-enal
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efficient cleavage in vitro
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?
torulene + O2
beta-apo-4'-carotenal + 3-methylbut-2-enal
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reaction is almost quantitative
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?
?
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cleavage at the third double bond from the uncycled tail of substrate. No substrate: bicyclic carotenes
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-
?
additional information
?
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cleavage at the third double bond from the uncycled tail of substrate. No substrate: bicyclic carotenes
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?