1.1.99.38: 2-deoxy-scyllo-inosamine dehydrogenase (AdoMet-dependent)
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For detailed information about 2-deoxy-scyllo-inosamine dehydrogenase (AdoMet-dependent), go to the full flat file.
Reaction
Synonyms
BtrN, DOIA dehydrogenase
ECTree
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Metals Ions
Metals Ions on EC 1.1.99.38 - 2-deoxy-scyllo-inosamine dehydrogenase (AdoMet-dependent)
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Iron
BtrNcontains a [4Fe-4S] cluster that delivers an electron to SAM, inducing its cleavage to the common intermediate in radical SAM reactions, the 5'-deoxyadenosyl 5'-radical. BtrN contains an additional [4Fe-4S] cluster, thought to bind in contact with the substrate to facilitate loss of the second electron in the two-electron oxidation
Iron
close interaction of both S-adenosyl-L-methionine and 2-deoxy-scyllo-inosamine with the [4Fe-4S] cluster