1.1.1.B51: 3-quinuclidinone reductase (NADPH)
This is an abbreviated version!
For detailed information about 3-quinuclidinone reductase (NADPH), go to the full flat file.
Reaction
Synonyms
RrQR
ECTree
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Substrates Products
Substrates Products on EC 1.1.1.B51 - 3-quinuclidinone reductase (NADPH)
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REACTION DIAGRAM
(R)-3-quinuclidinol + NADP+
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stereospecific reduction of 3-quinuclidinone
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3-quinuclidinone + NADPH + H+
(R)-3-quinuclidinol + NADP+
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stereospecific reduction of 3-quinuclidinone with over 85-95% enantiomeric excess, effects of concentration of 3-quinuclidinone hydrochloride, overview
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3-quinuclidinone + NADPH + H+
(R)-3-quinuclidinol + NADP+
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3-quinuclidinone + NADPH + H+
(R)-3-quinuclidinol + NADP+
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ethyl (S)-4-chloro-3-hydroxybutanoate + NADP+
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ethyl 4-chloro-3-oxobutanoate + NADPH + H+
ethyl (S)-4-chloro-3-hydroxybutanoate + NADP+
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pantoyl lactone + NADP+
the optical purity of pantoyl lactone is only 17.2% ee for L-isomer
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ketopantoyl lactone + NADPH + H+
pantoyl lactone + NADP+
the optical purity of pantoyl lactone is only 17.2% ee for L-isomer
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no activity with: acetaldehyde, propionaldehyde, heptanal, glyoxal, benzaldehyde, 2-nitrobenzaldehyde, 3-nitrobenzaldehyde, 4-nitrobenzaldehyde, 2-chlorobenzaldehyde, 3-chlorobenzaldehyde, pyridine-3-aldehyde, 2,4-pentanedione, 3-methylcyclohexanone, 4-methylcyclohexanone, 4-ethylcyclohexanone, isatin, p-toluquinone, alpha-naphthoquinone, menadione, ketoisophorone, levodione, 4-piperidone hydrochloride monohydrate, 1-methyl-4-piperidone, and tropinone
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additional information
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no activity with: acetaldehyde, propionaldehyde, heptanal, glyoxal, benzaldehyde, 2-nitrobenzaldehyde, 3-nitrobenzaldehyde, 4-nitrobenzaldehyde, 2-chlorobenzaldehyde, 3-chlorobenzaldehyde, pyridine-3-aldehyde, 2,4-pentanedione, 3-methylcyclohexanone, 4-methylcyclohexanone, 4-ethylcyclohexanone, isatin, p-toluquinone, alpha-naphthoquinone, menadione, ketoisophorone, levodione, 4-piperidone hydrochloride monohydrate, 1-methyl-4-piperidone, and tropinone
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