1.1.1.318: eugenol synthase
This is an abbreviated version!
For detailed information about eugenol synthase, go to the full flat file.
Word Map on EC 1.1.1.318
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1.1.1.318
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phenylpropene
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phenylpropanoids
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ocimum
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basilicum
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scent
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emit
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petunia
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basil
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o-methyltransferase
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hybrida
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floral
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cinnamyl
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methyleugenol
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petals
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ripe
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pollinator
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benzenoid
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trichomes
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ammonia-lyase
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strawberry
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peltate
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estragole
- 1.1.1.318
-
phenylpropene
-
phenylpropanoids
- ocimum
- basilicum
-
scent
-
emit
- petunia
- basil
-
o-methyltransferase
- hybrida
-
floral
-
cinnamyl
- methyleugenol
- petals
-
ripe
-
pollinator
-
benzenoid
-
trichomes
-
ammonia-lyase
- strawberry
-
peltate
- estragole
Reaction
Synonyms
CbEGS1, CbEGS2, chavicol/eugenol synthase, DcE(I)GS1, DcEGS1, EGS, EGS1, EGS2, eugenol synthase 1, eugenol synthase 2, eugenol synthase 3, eugenol synthase 4, eugenol synthase 5, eugenol synthase 6, eugenol synthase 7, eugenol synthase 8, eugenol/isoeugenol synthase, IEGS1, IEGS2, LtCES1, More, ObEGS1, ObEGS2, ObEGS3, ObEGS4, ObEGS5, ObEGS6, ObEGS7, ObEGS8, PhEGS1, RcEGS1, RhEGS1
ECTree
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Reaction
Reaction on EC 1.1.1.318 - eugenol synthase
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eugenol + a carboxylate + NADP+ = a coniferyl ester + NADPH + H+
reaction mechanism, overview
eugenol + a carboxylate + NADP+ = a coniferyl ester + NADPH + H+
reaction mechanism, detailed overview
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eugenol + a carboxylate + NADP+ = a coniferyl ester + NADPH + H+
eugenol synthase catalyzes the reductive displacement of acetate from the propenyl side chain of the substrate coniferyl acetate to produce the allyl-phenylpropene eugenol, two-step reaction mechanism involving the formation of a quinone-methide prior to reduction, overview. The formation of this intermediate is promoted by a hydrogen-bonding network that favors deprotonation of the substrate's 4-hydroxyl group and disfavors binding of the acetate moiety, akin to a push-pull catalytic mechanism, involvement of a quinone-methide, a conjugated enone, intermediate in the bond cleavage