1.1.1.236: tropinone reductase II
This is an abbreviated version!
For detailed information about tropinone reductase II, go to the full flat file.
Word Map on EC 1.1.1.236
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1.1.1.236
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tropane
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reductases
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stramonium
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datura
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scopolamine
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calystegines
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solanaceae
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hyoscyamine
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hyoscyamus
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tuberosum
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solanum
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tuber
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solanaceous
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alkaloid-producing
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n-methylputrescine
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3-quinuclidinone
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enemies
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stereoisomeric
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herbivores
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n-methyltransferase
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nortropane
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nonmetal
- 1.1.1.236
-
tropane
- reductases
- stramonium
- datura
- scopolamine
-
calystegines
- solanaceae
- hyoscyamine
-
hyoscyamus
- tuberosum
-
solanum
- tuber
-
solanaceous
-
alkaloid-producing
- n-methylputrescine
- 3-quinuclidinone
-
enemies
-
stereoisomeric
-
herbivores
- n-methyltransferase
-
nortropane
-
nonmetal
Reaction
Synonyms
DnTR2, More, pseudotropine forming tropinone reductase, pseudotropine reductase II, pseudotropine-forming tropinone reductase, pseudotropinone forming tropinone reductase, TR-II, TR2, TRII, tropinone (psi-tropine-forming) reductase, tropinone reductase, tropinone reductase I, tropinone reductase II, tropinone reductase-II
ECTree
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Natural Substrates Products
Natural Substrates Products on EC 1.1.1.236 - tropinone reductase II
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REACTION DIAGRAM
tropinone + NADPH + H+
pseudotropine + NADP+
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?
tropinone + NADPH + H+
pseudotropine + NADP+
reaction of tropinone reductase II, EC 1.1.1.236, tropane alkaloid biosynthesis, overview
leading to formation of calystegines
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?
tropinone + NADPH + H+
pseudotropine + NADP+
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?
tropinone + NADPH + H+
pseudotropine + NADP+
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pseudotropine oxidation never observed
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ir
tropinone + NADPH + H+
pseudotropine + NADP+
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?
tropinone + NADPH + H+
pseudotropine + NADP+
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reverse reaction very inefficient, about 1.3% of the forward activity
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r
tropinone + NADPH + H+
pseudotropine + NADP+
direction of biosynthesis
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r
tropinone + NADPH + H+
pseudotropine + NADP+
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the enzyme is involved in tropane alkaloid biosynthesis, overview
leading to formation of calystegines
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?
tropinone + NADPH + H+
pseudotropine + NADP+
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Solanum tuberosum tropinone reductase II reduces tropinone in vivo
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r
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the bifunctional enzyme of Cochlearia officinalis is not stereospecific, in contrast to the Solanaceae species, and catalyzes both tropinone reductase reactions, a tyrosine residue in the active site of Cochlearia officinalis TR is responsible for binding and orientation of tropinone, overview
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